European Union and the Free State of Saxony. Grant Number: 100099597

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European Union and the Free State of Saxony. Grant Number: 100099597

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Publications

Binuclear dichlorido(eta(6)-p-cymene)ruthenium(II) complexes with bis(nicotinate)- and bis (isonicotinate)-polyethylene glycol ester ligands

Eichhorn, Thomas; Hey-Hawkins, Evamarie; Maksimović-Ivanić, Danijela; Mojić, Marija; Schmidt, Juergen; Mijatović, Sanja; Schmidt, Harry; Kaluđerović, Goran N.

(2015)

TY  - JOUR
AU  - Eichhorn, Thomas
AU  - Hey-Hawkins, Evamarie
AU  - Maksimović-Ivanić, Danijela
AU  - Mojić, Marija
AU  - Schmidt, Juergen
AU  - Mijatović, Sanja
AU  - Schmidt, Harry
AU  - Kaluđerović, Goran N.
PY  - 2015
UR  - https://radar.ibiss.bg.ac.rs/handle/123456789/2099
AB  - Neutral binuclear ruthenium complexes 1, 2, 3, 4, 5, 6, 7, 8 of the
   general formula {[}\{RuCl2((6)-p-cym)\}(2)-(NN)] (NN=bis(nicotinate)-
   and bis(isonicotinate)-polyethylene glycol esters:
   (3-py)COO(CH2CH2O)(n)CO(3-py) and (4-py)COO(CH2CH2O)(n)CO(4-py), n
   =1-4), as well as mononuclear
   {[}RuCl2((6)-p-cym)((3-py)COO(CH2CH2OCH3)-N)], complex 9, were
   synthesized and characterized using elemental analysis and electrospray
   ionization high-resolution mass spectrometry, infrared, H-1 NMR and C-13
   NMR spectroscopies. Stability of the binuclear complexes in the presence
   of dimethylsulfoxide was studied. Furthermore, formation of a cationic
   complex containing bridging pyridine-based bidentate ligand was
   monitored using H-1 NMR spectroscopy. Ligand precursors, polyethylene
   glycol esters of nicotinic (L12HCl-L42HCl and L9HCl) and isonicotinic
   acid dihydrochlorides (L52HCl-L82HCl), binuclear ruthenium(II) complexes
   1, 2, 3, 4, 5, 6, 7, 8 and mononuclear complex 9 were tested for in
   vitro cytotoxicity against 518A2 (melanoma), 8505C (anaplastic thyroid
   cancer), A253 (head and neck tumour), MCF-7 (breast tumour) and SW480
   (colon carcinoma) cell lines. Copyright (c) 2014 John Wiley \& Sons,
   Ltd.
T2  - Applied Organometallic Chemistry
T1  - Binuclear dichlorido(eta(6)-p-cymene)ruthenium(II) complexes with
 bis(nicotinate)- and bis (isonicotinate)-polyethylene glycol ester
 ligands
IS  - 1
VL  - 29
DO  - 10.1002/aoc.3238
SP  - 20
EP  - 25
ER  - 
@article{
author = "Eichhorn, Thomas and Hey-Hawkins, Evamarie and Maksimović-Ivanić, Danijela and Mojić, Marija and Schmidt, Juergen and Mijatović, Sanja and Schmidt, Harry and Kaluđerović, Goran N.",
year = "2015",
abstract = "Neutral binuclear ruthenium complexes 1, 2, 3, 4, 5, 6, 7, 8 of the
   general formula {[}\{RuCl2((6)-p-cym)\}(2)-(NN)] (NN=bis(nicotinate)-
   and bis(isonicotinate)-polyethylene glycol esters:
   (3-py)COO(CH2CH2O)(n)CO(3-py) and (4-py)COO(CH2CH2O)(n)CO(4-py), n
   =1-4), as well as mononuclear
   {[}RuCl2((6)-p-cym)((3-py)COO(CH2CH2OCH3)-N)], complex 9, were
   synthesized and characterized using elemental analysis and electrospray
   ionization high-resolution mass spectrometry, infrared, H-1 NMR and C-13
   NMR spectroscopies. Stability of the binuclear complexes in the presence
   of dimethylsulfoxide was studied. Furthermore, formation of a cationic
   complex containing bridging pyridine-based bidentate ligand was
   monitored using H-1 NMR spectroscopy. Ligand precursors, polyethylene
   glycol esters of nicotinic (L12HCl-L42HCl and L9HCl) and isonicotinic
   acid dihydrochlorides (L52HCl-L82HCl), binuclear ruthenium(II) complexes
   1, 2, 3, 4, 5, 6, 7, 8 and mononuclear complex 9 were tested for in
   vitro cytotoxicity against 518A2 (melanoma), 8505C (anaplastic thyroid
   cancer), A253 (head and neck tumour), MCF-7 (breast tumour) and SW480
   (colon carcinoma) cell lines. Copyright (c) 2014 John Wiley \& Sons,
   Ltd.",
journal = "Applied Organometallic Chemistry",
title = "Binuclear dichlorido(eta(6)-p-cymene)ruthenium(II) complexes with
 bis(nicotinate)- and bis (isonicotinate)-polyethylene glycol ester
 ligands",
number = "1",
volume = "29",
doi = "10.1002/aoc.3238",
pages = "20-25"
}
Eichhorn, T., Hey-Hawkins, E., Maksimović-Ivanić, D., Mojić, M., Schmidt, J., Mijatović, S., Schmidt, H.,& Kaluđerović, G. N.. (2015). Binuclear dichlorido(eta(6)-p-cymene)ruthenium(II) complexes with
 bis(nicotinate)- and bis (isonicotinate)-polyethylene glycol ester
 ligands. in Applied Organometallic Chemistry, 29(1), 20-25.
https://doi.org/10.1002/aoc.3238
Eichhorn T, Hey-Hawkins E, Maksimović-Ivanić D, Mojić M, Schmidt J, Mijatović S, Schmidt H, Kaluđerović GN. Binuclear dichlorido(eta(6)-p-cymene)ruthenium(II) complexes with
 bis(nicotinate)- and bis (isonicotinate)-polyethylene glycol ester
 ligands. in Applied Organometallic Chemistry. 2015;29(1):20-25.
doi:10.1002/aoc.3238 .
Eichhorn, Thomas, Hey-Hawkins, Evamarie, Maksimović-Ivanić, Danijela, Mojić, Marija, Schmidt, Juergen, Mijatović, Sanja, Schmidt, Harry, Kaluđerović, Goran N., "Binuclear dichlorido(eta(6)-p-cymene)ruthenium(II) complexes with
 bis(nicotinate)- and bis (isonicotinate)-polyethylene glycol ester
 ligands" in Applied Organometallic Chemistry, 29, no. 1 (2015):20-25,
https://doi.org/10.1002/aoc.3238 . .
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